Synthesis of highly piezoelectric lead-free (K, Na)NbO3 one-dimensional perovskite nanostructures

被引:51
作者
Cheng, Li-Qian [1 ]
Wang, Ke [1 ]
Li, Jing-Feng [1 ]
机构
[1] Tsinghua Univ, Sch Mat Sci & Engn, State Key Lab New Ceram & Fine Proc, Beijing 100084, Peoples R China
关键词
TITANATE NANOTUBES; ZIRCONATE-TITANATE; FREE PIEZOCERAMICS; NANOWIRE; CERAMICS;
D O I
10.1039/c3cc41371c
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
High-aspect-ratio single-crystalline KNN nanorods (length similar to 10-20 mu m and diameter similar to 400 nm) are synthesized using a facile method based on a molten-salt reaction, whose formation mechanism has been revealed. The lead-free piezoelectric nanorods showing high piezoelectric coefficient d*(33) up to similar to 230 pm V-1 may be used in biosensing and energy-harvesting micro-devices.
引用
收藏
页码:4003 / 4005
页数:3
相关论文
共 25 条
[1]   Morphotropic phase boundary and electrical properties of K1-xNaxNbO3 lead-free ceramics [J].
Dai, Ye-Jing ;
Zhang, Xiao-Wen ;
Chen, Ke-Pi .
APPLIED PHYSICS LETTERS, 2009, 94 (04)
[2]   Synthesis and Characterization of Bowl-Like Single-Crystalline BaTiO3 Nanoparticles [J].
Deng, Zhao ;
Dai, Ying ;
Chen, Wen ;
Pei, Xinmei ;
Liao, Jihong .
NANOSCALE RESEARCH LETTERS, 2010, 5 (07) :1217-1221
[3]   Chemical control of octahedral tilting and off-axis A cation displacement allows ferroelectric switching in a bismuth-based perovskite [J].
Dolgos, M. ;
Adem, U. ;
Wan, X. ;
Xu, Z. ;
Bell, A. J. ;
Comyn, T. P. ;
Stevenson, T. ;
Bennett, J. ;
Claridge, J. B. ;
Rosseinsky, M. J. .
CHEMICAL SCIENCE, 2012, 3 (05) :1426-1435
[4]   Facile synthesis and high d33 of single-crystalline KNbO3 nanocubes [J].
Ge, Haiyan ;
Hou, Yudong ;
Zhu, Mankang ;
Wang, Hao ;
Yan, Hui .
CHEMICAL COMMUNICATIONS, 2008, (41) :5137-5139
[5]   In-plane aligned Pb(ZrxTi1-x)O3 microbelts fabricated by near migration and restricted growth [J].
Gong, W ;
Li, JF ;
Peng, CE ;
Gui, ZL ;
Li, LT .
ADVANCED MATERIALS, 2005, 17 (16) :1952-+
[6]   Lithium Ion Intercalation Performance of Niobium Oxides: KNb5O13 and K6Nb10.8O30 [J].
Han, Jian-Tao ;
Liu, Dong-Qiang ;
Song, Sang-Hoon ;
Kim, Youngsik ;
Goodenough, John B. .
CHEMISTRY OF MATERIALS, 2009, 21 (20) :4753-4755
[7]   Growth of Pb(Fe1/2Nb1/2)O3-Pb(Yb1/2Nb1/2)O3-PbTiO3 piezo-/ferroelectric crystals for high power and high temperature applications [J].
He, Chao ;
Li, Xiuzhi ;
Wang, Zujian ;
Liu, Ying ;
Shen, Dongquan ;
Li, Tao ;
Long, Xifa ;
Ye, Zuo-Guang .
CRYSTENGCOMM, 2012, 14 (13) :4407-4413
[8]   FORMATION OF LEAD NIOBATES IN MOLTEN-SALT SYSTEMS [J].
LI, CC ;
CHIU, CC ;
DESU, SB .
JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 1991, 74 (01) :42-47
[9]   Phase Evolution in Low-Dimensional Niobium Oxide Synthesized by a Topochemical Method [J].
Li, Lihong ;
Deng, Jinxia ;
Yu, Ranbo ;
Chen, Jun ;
Wang, Xiaowei ;
Xing, Xianran .
INORGANIC CHEMISTRY, 2010, 49 (04) :1397-1403
[10]   Ferroelectric lead zirconate titanate and barium titanate nanotubes [J].
Luo, Y ;
Szafraniak, I ;
Nagarajan, V ;
Wehrspohn, RB ;
Steinhart, M ;
Wendorff, JH ;
Zakharov, ND ;
Ramesh, R ;
Alexe, M .
INTEGRATED FERROELECTRICS, 2003, 59 :1513-1520