Activation of carbon nanotube emitters by using supercritical carbon dioxide fluids with propyl alcohol

被引:11
作者
Liu, PT [1 ]
Tsai, CT
Chang, TC
Kin, KT
Chang, PL
Chen, CM
Cheng, HF
机构
[1] Natl Chiao Tung Univ, Dept Photon, Hsinchu 300, Taiwan
[2] Natl Chiao Tung Univ, Display Inst, Hsinchu 300, Taiwan
[3] Natl Tsing Hua Univ, Inst Elect Engn, Hsinchu 300, Taiwan
[4] Natl Sun Yat Sen Univ, Dept Phys, Ctr Nanosci & Nanotechnol, Kaohsiung 80424, Taiwan
[5] Natl Sun Yat Sen Univ, Inst Electroopt Engn, Ctr Nanosci & Nanotechnol, Kaohsiung 80424, Taiwan
[6] Ind Technol Res Inst, Energy & Resources Labs, Hsinchu 31015, Taiwan
关键词
D O I
10.1149/1.2170484
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
This paper explores the application of supercritical carbon dioxide fluids on the field emission enhancement for vertically aligned carbon nanotubes. The typical heating process cannot effectively activate the deionized-water-rinsed carbon nanotube emitters, exhibiting poorer field emission performance, due to residual moisture uptake in the carbon nanotubes. In contrast, the field emission enhancement can be achieved significantly by applying the supercritical carbon dioxide fluids associated with 3 to 9 vol % propyl alcohol. It is found the cosolvent propyl alcohol plays a critical role in the activation efficiency of supercritical carbon dioxide fluids. A physical model is also deduced to clarify the observation. (c) 2006 The Electrochemical Society.
引用
收藏
页码:G124 / G126
页数:3
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