Transition metal complex exciplexes

被引：45

作者：

Horvath, A ^{[1
]}

Stevenson, KL ^{[1
]}

机构：

[1] INDIANA UNIV PURDUE UNIV,DEPT CHEM,FT WAYNE,IN 46805

来源：

COORDINATION CHEMISTRY REVIEWS | 1996年 / 153卷

基金：

美国国家科学基金会; 匈牙利科学研究基金会;

关键词：

transition metal complexes; exciplexes; photophysical properties; photochemical properties; reactive sites; electronic structure;

D O I：

10.1016/0010-8545(95)01227-3

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The photophysical and photochemical properties of exciplexes are summarized considering the electronic structure and role of energetics and kinetics in the formation and stabilization of these molecular entities. Exciplexes involving transition metal complexes, are known as transition metal complex exciplexes (TMCEs) and are classified on the basis of the reactive site of the excited metal complex and the properties of the ground state reactant. There are two main groups; ligand-centered exciplexes and metal-centered exciplexes, A survey of the literature of TMCEs is presented. Common features of excipIexes classified into different groups are revealed. A strategy for searching for new TMCEs is suggested.

引用

页码：57 / 82

页数：26

共 45 条

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