Synthesis and characterization of an organically-templated zincophosphite:: [C6H16N2]•Zn3(HPO3)4

被引：14

作者：

Fu, WS ^{[1
]}

Shi, Z ^{[1
]}

Li, GN ^{[1
]}

Zhang, D ^{[1
]}

Dong, WJ ^{[1
]}

Chen, XB ^{[1
]}

Feng, SH ^{[1
]}

机构：

[1] Jilin Univ, Coll Chem, State Key Lab Inorgan Synth & Preparat Chem, Changchun 130023, Peoples R China

来源：

SOLID STATE SCIENCES | 2004年 / 6卷 / 02期

基金：

中国国家自然科学基金;

关键词：

zincophosphite; mixed solvothermal synthesis; structure; organically-templated;

D O I：

10.1016/j.solidstatesciences.2003.12.009

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A novel three-dimensional zincophosphite templated by N,N'-dimethylpiperazine, [C6H16N2]Zn-.(3)(HPO3)(4), has been synthesized under mild mixed solvothermal conditions and characterized by X-ray crystallography, differential thermal-thermogravimetric analysis (TG-DTA), P-31 MAS NMR spectrum and IR spectroscopy. The compound crystallizes in the orthorhombic system, space group Pbcn, a = 12.7975 (3) Angstrom, b = 10.2182(3) Angstrom, c = 14.8305(5) Angstrom, V = 1939.35(10) Angstrom(3), Z = 4, Dc = 2.165 g cm(-3), mu = 4.070 mm(-1). The structure consists of a network of strictly alternating ZnO4 tetrahedra and [HPO32-] pseudo-pyramid forming tripled 4-membered ring chains. This compound exhibits a three-dimensional structure with 8-membered ring channels where the completely protonated N,N'-dimethylpiperazine cations are located. (C) 2004 Elsevier SAS. All rights reserved.

引用

页码：225 / 228

页数：4

共 33 条

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