Pronounced catalytic effect of micellar solution of sodium dodecyl sulfate (SDS) for regioselective iodination of aromatic compounds with a sodium iodide/cerium(IV) trihydroxide hydroperoxide system

被引:70
作者
Firouzabadi, H [1 ]
Iranpoor, N [1 ]
Garzan, A [1 ]
机构
[1] Shiraz Univ, Coll Sci, Dept Chem, Shiraz 71454, Iran
关键词
aromatic compounds; cerium(IV) trihydroxide hydroperoxide; iodination; sodium dodecyl sulfate; sodium iodide;
D O I
10.1002/adsc.200505222
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
Micellar solutions of sodium dodecyl sulfate (SDS) catalyze the regioselective iodination of a wide range of aromatic compounds with sodium iodide in the presence of the easily prepared, water-resistant and recyclable cerium(IV) trihydroxide hydroperoxide, Ce(OH)(3)O2H, at room temperature. By this protocol, structurally diverse aromatic compounds including benzene and naphthalene were iodinated in good to excellent yields.
引用
收藏
页码:1925 / 1928
页数:4
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