Transition-metal-free: A highly efficient catalytic aerobic alcohol oxidation process

被引：396

作者：

Liu, RH ^{[1
]}

Liang, XM ^{[1
]}

Dong, CY ^{[1
]}

Hu, XQ ^{[1
]}

机构：

[1] Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2004年 / 126卷 / 13期

关键词：

D O I：

10.1021/ja031765k

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A highly efficient catalytic system without transition metals has been developed for aerobic alcohol oxidations. Under the optimal reaction conditions, various alcohol substrates were converted into their corresponding carbonyl compounds by air with TEMPO/Br2/NaNO2 as catalyst, especially the oxidation of benzylic alcohols to benzaldehydes in high yields. Copyright © 2004 American Chemical Society.

引用

页码：4112 / 4113

页数：2

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