Effect of different sized CeO2 nano particles on decomposition and hydrogen absorption kinetics of magnesium hydride

被引：69

作者：

Singh, Rajesh Kumar ^{[1
,2
]}

Sadhasivam, T. ^{[1
]}

Sheeja, G. I. ^{[1
]}

Singh, P. ^{[2
]}

Srivastava, O. N. ^{[1
]}

机构：

[1] Banaras Hindu Univ, Dept Phys, Hydrogen Energy & Nanosci Ctr, Varanasi 221005, Uttar Pradesh, India

[2] Banaras Hindu Univ, Dept Appl Phys, Indian Inst Technol, Varanasi 221005, Uttar Pradesh, India

来源：

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY | 2013年 / 38卷 / 14期

关键词：

Hydrogen storage materials; Isothermal desorption; Kinetics; SORPTION PROPERTIES; STORAGE; MGH2; MICROSTRUCTURE; OXIDES; NB2O5; CR2O3;

D O I：

10.1016/j.ijhydene.2012.12.060

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

In present paper, different sizes of CeO2 nanoparticles were synthesized by ball milling and their effect on the absorption kinetics and decomposition temperature of MgH2 was studied. It was found that a small amount of admixing of the above said catalysts with MgH2 exhibits improved hydrogen storage properties. Among these different sizes of CeO2 nanoparticles, 2 weight % admixed CeO2 with a particle size of similar to 10-15 nm led to decrease in desorption temperature by similar to 50 K. Moreover, it also shows 1.5 times better absorption kinetics with respect to pure MgH2. The samples were characterized using SEM, TEM and XRD techniques. The hydrogenation/dehydrogenation properties were measured by gas reaction controller. Copyright (C) 2012, Hydrogen Energy Publications, LLC. Published by Elsevier Ltd. All rights reserved.

引用

页码：6221 / 6225

页数：5

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