Diverse Organic Field-Effect Transistor Sensor Responses from Two Functionalized Naphthalenetetracarboxylic Diimides and Copper Phthalocyanine Semiconductors Distinguishable Over a Wide Analyte Range

被引:57
作者
Huang, Weiguo [1 ]
Sinha, Jasmine [1 ]
Yeh, Ming-Ling [1 ]
Hardigree, Josue F. Martinez [1 ]
LeCover, Rachel [1 ]
Besar, Kalpana [1 ]
Rule, Ana Maria [2 ]
Breysse, Patrick N. [2 ]
Katz, Howard E. [1 ]
机构
[1] Johns Hopkins Univ, Dept Mat Sci & Engn & Chem, Baltimore, MD 21218 USA
[2] Johns Hopkins Univ, Bloomberg Sch Publ Hlth, Dept Environm Hlth Sci, Baltimore, MD 21205 USA
基金
美国国家科学基金会;
关键词
sensor arrays; naphthalenetetracarboxylic diimide; copper phthalocyanine; organic field-effect transistors; THIN-FILM-TRANSISTOR; SELECTIVE DETECTION; HYDROGEN-PEROXIDE; CARBON NANOTUBES; CHEMICAL SENSORS; VAPOR DETECTION; QCM SENSORS; GAS SENSORS; ARRAYS; CHEMIRESISTORS;
D O I
10.1002/adfm.201300245
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Naphthalenetetracarboxylic diimide derivatives (octyl 8 NTCDI, dimethylaminopropyl DMP NTCDI) and copper phthalocyanine (CuPc) are used to form a diverse organic field-effect transistor (OFET) sensor array. CuPc and 8-NTCDI are p-channel and n-channel semiconductors, respectively, showing expected and opposing responses to analytes. DMP-NTCDI, on the other hand, because of its ionizable side chain, shows response directions and magnitudes that are not correlated to those of the other two. The result is a distinct response pattern and unambiguous recognition ability for individual analytes. The differences are even more dramatic if the time evolution of the responses is considered. The three-response patterns obtained from representative polar, nonpolar, acidic, and basic vapors are all different, showing the potential for this approach in rapid, low-cost electronic detection of volatile compounds.
引用
收藏
页码:4094 / 4104
页数:11
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