Molecular measurements of methane hydrate formation

被引：99

作者：

Subramanian, S ^{[1
]}

Sloan, ED ^{[1
]}

机构：

[1] Colorado Sch Mines, Ctr Hydrate Res, Golden, CO 80401 USA

来源：

FLUID PHASE EQUILIBRIA | 1999年 / 158卷

关键词：

Raman spectroscopy; kinetics; hydrates;

D O I：

10.1016/S0378-3812(99)00134-X

中图分类号：

O414.1 [热力学];

学科分类号：

摘要：

Time-wise Raman data are presented as evidence for methane transformation to the hydrate phase from methane dissolved in water for three cases: (1) pure water, (2) water containing a kinetic inhibitor, Poly N-vinylcaprolactam (PVCap), and (3) water containing 1 wt.% deuterated tetrahydrofuran (THF-d(8)). The ratio of large to small cage formation is suggested as a basis for a future kinetic model. (C) 1999 Elsevier Science B.V. All rights reserved.

引用

页码：813 / 820

页数：8

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