Two-photon photolysis of CF3Cl at 10.5 eV:: determination of the Cl/Cl spin-orbit branching ratio and the formation of electronically excited CF3

被引：3

作者：

Ardelt, D ^{[1
]}

Stuhl, F ^{[1
]}

机构：

[1] Ruhr Univ Bochum, D-44780 Bochum, Germany

来源：

CHEMICAL PHYSICS LETTERS | 1999年 / 304卷 / 5-6期

关键词：

D O I：

10.1016/S0009-2614(99)00303-6

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The (5e)(-1) 4p Rydberg state of CF3Cl at about 10.5 eV has been excited by a two-photon absorption process. The photodissociation into the individual spin states Cl*( P-1/2) and Cl(P-2(3/2)) has been monitored together with the formation of electronically excited C-3*. These fragments were detected by (2 + 1)REMPI(CI) or photoionzation (CF3*). The state distribution ratio R = Cl*/(Cl* + Cl) was determined to be 0.10 +/- 0.05, which is significantly non-statistical. (C) 1999 Elsevier Science B.V. All rights reserved.

引用

页码：323 / 328

页数：6

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Two-photon photolysis of CF3Cl at 10.5 eV:: determination of the Cl*/Cl spin-orbit branching ratio and the formation of electronically excited CF3*

Two-photon photolysis of CF3Cl at 10.5 eV:: determination of the Cl/Cl spin-orbit branching ratio and the formation of electronically excited CF3