Hexathienocoronenes: Synthesis and Self-Organization

被引：86

作者：

Chen, Long ^{[1
]}

Puniredd, Sreenivasa R. ^{[1
]}

Tan, Yuan-Zhi ^{[1
]}

Baumgarten, Martin ^{[1
]}

Zschieschang, Ute ^{[2
]}

Enkelmann, Volker ^{[1
]}

Pisula, Wojciech ^{[1
]}

Feng, Xinliang ^{[1
]}

Klauk, Hagen ^{[2
]}

Muellen, Klaus ^{[1
]}

机构：

[1] Max Planck Inst Polymer Res, D-55128 Mainz, Germany

[2] Max Planck Inst Solid State Res, D-70569 Stuttgart, Germany

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2012年 / 134卷 / 43期

关键词：

DISCOTIC LIQUID-CRYSTALS; FIELD-EFFECT TRANSISTORS; ISOMERICALLY PURE; HIGH-PERFORMANCE; ORGANIC TRANSISTORS; EFFECT MOBILITY; MOLECULE; EFFICIENCY; AMBIPOLAR; KETONES;

D O I：

10.1021/ja3082395

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Here we report hexathienocoronenes (HTCs), fully thiophene-annelated coronenes in which six double bonds in the periphery are thieno-fused. The derivatives tetrasubstituted with hexyl and dodecyl chains show a phase formation that strongly depends on the chain length. HTCs are remarkably stronger donors than the known thiophene-annelated coronenes but do not readily assemble into well-ordered films when deposited from the vapor phase. Thus, thin-film transistors fabricated by vacuum deposition have only modest field-effect mobilities of 0.002 cm(2) V-1 s(-1).

引用

页码：17869 / 17872

页数：4

共 62 条

[1] Dimers of Anthrathiophene and Anthradithiophene Derivatives: Synthesis and Characterization [J].