Experimental and model studies of oscillations, photoinduced transitions, and steady states in the Ru(bPY)32+-catalyzed Belousov-Zhabotinsky reaction under different solute compositions

被引：27

作者：

Amemiya, T

Yamamoto, T

Ohmori, T

Yamaguchi, T

机构：

[1] Natl Inst Adv Ind Sci & Technol, Nanotechnol Res Inst, Tsukuba, Ibaraki 3058565, Japan

[2] Natl Inst Adv Ind Sci & Technol, Res Inst Green Technol, Tsukuba, Ibaraki 3058565, Japan

来源：

JOURNAL OF PHYSICAL CHEMISTRY A | 2002年 / 106卷 / 04期

关键词：

D O I：

10.1021/jp012717u

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Experiments of the Ru(bPY)(3)(2+)-catalyzed Belousov-Zhabotinsky (BZ) reaction exhibited several types of oscillations, photoinduced transitions, and steady states in a continuous-flow stirred tank reactor (CSTR) system under a wide range of oxidative and reductive solute conditions. An improved Oregonator-class model of the photosensitive BZ reaction has reproduced the experimental behavior quantitatively as well as other photoinduced behavior reported so far.

引用

收藏

页码：612 / 620

页数：9

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