Temperature effect on the lithium diffusion rate in graphite

被引：85

作者：

Kulova, TL ^{[1
]}

Skundin, AM ^{[1
]}

Nizhnikovskii, EA ^{[1
]}

Fesenko, AV ^{[1
]}

机构：

[1] Russian Acad Sci, AN Frumkin Electrochem Inst, Moscow 119071, Russia

来源：

RUSSIAN JOURNAL OF ELECTROCHEMISTRY | 2006年 / 42卷 / 03期

关键词：

intercalation; lithium diffusion coefficient; activation energy for diffusion;

D O I：

10.1134/S1023193506030086

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 [应用化学];

摘要：

The temperature influence on the diffusion coefficient for lithium in graphite is investigated. The activation energy for lithium diffusion in graphite is calculated. Its value is 35 kJ mol(-1).

引用

页码：259 / 262

页数：4

共 28 条

[1]

THE STUDY OF LI-GRAPHITE INTERCALATION PROCESSES IN SEVERAL ELECTROLYTE SYSTEMS USING IN-SITU X-RAY-DIFFRACTION [J].

AURBACH, D ;

EINELI, Y .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1995, 142 (06) :1746-1752

[2]

Kinetics of lithium intercalation into carbon anodes: in situ impedance investigation of thickness and potential dependence [J].

Barsoukov, E ;

Kim, JH ;

Yoon, CO ;

Lee, H .

SOLID STATE IONICS, 1999, 116 (3-4) :249-261

[3]

EXFOLIATION OF GRAPHITE [J].

CHUNG, DDL .

JOURNAL OF MATERIALS SCIENCE, 1987, 22 (12) :4190-4198

[4]

CHURIKOV AV, 2002, ELEKTROKHIMIYA, V38, P126

[5]

A transient method for measuring diffusion coefficients of thin film battery electrodes - Results for LiyCoO2 and LixC6 thin films [J].

Goldner, RB ;

Liu, TY ;

Slaven, S .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1996, 143 (06) :L129-L130

[6]

Electrochemical intercalation of lithium species into disordered carbon prepared by the heat-treatment of poly (p-phenylene) at 650°C for anode in lithium-ion battery [J].

Gong, JB ;

Wu, HQ .

ELECTROCHIMICA ACTA, 2000, 45 (11) :1753-1762

[7]

LI METAL-FREE RECHARGEABLE LIMN2O4/CARBON CELLS - THEIR UNDERSTANDING AND OPTIMIZATION [J].

GUYOMARD, D ;

TARASCON, JM .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1992, 139 (04) :937-948

[8]

Rapid diffusion of lithium into bulk graphite in lithium conditioning [J].

Itou, N ;

Toyoda, H ;

Morita, K ;

Sugai, H .

JOURNAL OF NUCLEAR MATERIALS, 2001, 290 (290-293) :281-285

[9]

IVANISHCHEV AV, 2003, ELEKTROKHIM ENERG, V3, P174

[10]

ELECTROCHEMICAL AND STRUCTURAL STUDIES OF PETROLEUM COKE IN CARBONATE-BASED ELECTROLYTES [J].

JEAN, M ;

DESNOYER, C ;

TRANCHANT, A ;

MESSINA, R .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1995, 142 (07) :2122-2125

← 1 2 3 →