A copper-complexed rotaxane in motion: pirouetting of the ring on the millisecond timescale

被引：117

作者：

Poleschak, I ^{[1
]}

Kern, JM ^{[1
]}

Sauvage, JP ^{[1
]}

机构：

[1] Univ Strasbourg, CNRS, UMR 7513, Lab Chim Organominerale,Fac Chim, F-67070 Strasbourg, France

来源：

CHEMICAL COMMUNICATIONS | 2004年 / 04期

关键词：

D O I：

10.1039/b315080a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A new bistable rotaxane, consisting of a 2,2'-bipyridine-containing thread and a ring incorporating both a bidentate chelate and a tridentate fragment, has been prepared; this complex undergoes an electrochemically driven pirouetting motion of the ring around the axis which takes place on the millisecond timescale, i.e. several orders of magnitude faster than the other copper-based machines previously described.

引用

页码：474 / 476

页数：3

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