Effect of degumming on the tensile properties of silkworm (Bombyx mori) silk fiber

被引:101
作者
Pérez-Rigueiro, J
Elices, M
Llorca, J
Viney, C
机构
[1] Univ Politecn Madrid, Dept Ciencia Mat, ETS Ingenieros Caminos, E-28040 Madrid, Spain
[2] Heriot Watt Univ, Dept Chem, Edinburgh EH14 4AS, Midlothian, Scotland
关键词
D O I
10.1002/app.10366
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
Forcibly reeled silkworm (Bombyx mori) silk was used to study how exposure to a degumming treatment (boiling in distilled water for 30 min) affects tensile properties. Because forcibly reeled and naturally spun fibers exhibit comparable mechanical behavior, the results can be generalized to material obtained conventionally from cocoons. The effects of degumming include: a decrease in the initial elastic modulus, a decrease in the stress at the proportional limit (yield strength), a change in the qualitative shape of force-displacement curves, and significant qualitative and quantitative variability in force-displacement data from samples subjected to nominally identical degumming histories. Immersion in water at room temperature or heating in air at 100degreesC for 30 min are both qualitatively equivalent to a 30-min degumming treatment in boiling water, in terms of the effect on silk tensile properties. (C) 2002 Wiley Periodicals, Inc.
引用
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页码:1431 / 1437
页数:7
相关论文
共 21 条
[1]  
Asakura T., 1994, Encyclopedia of AgriculturalScience, P1
[2]   TENSILE MECHANICAL PROPERTY EVALUATION OF NATURAL AND EPOXIDE-TREATED SILK FIBERS [J].
DUNAWAY, DL ;
THIEL, BL ;
VINEY, C .
JOURNAL OF APPLIED POLYMER SCIENCE, 1995, 58 (03) :675-683
[3]  
ELICES M, 2000, PERGAMON MAT SERIES
[4]  
Iizuka E, 1985, J APPL POLYM SCI APP, V41, P173
[5]  
Israelachvili J. N., 1992, INTERMOLECULAR SURFA
[6]   STRUCTURE AND CHEMICAL-COMPOSITION OF SILK PROTEINS IN RELATION TO SILKWORM DIET [J].
ITO, H ;
MURAOKA, Y ;
YAMAZAKI, T ;
IMAMURA, T ;
MORI, H ;
ICHIDA, M ;
SUMIDA, M ;
MATSUBARA, F .
TEXTILE RESEARCH JOURNAL, 1995, 65 (12) :755-759
[7]  
Kaplan D.L., 1991, BIOMATERIALS NOVEL M, P1
[8]   Influence of steam treatment on crystalline regions of silks [J].
Kawahara, Y .
TEXTILE RESEARCH JOURNAL, 1998, 68 (05) :385-385
[9]  
Lucas F., 1955, J TEXT I, V46, P440
[10]   AN INVESTIGATION OF THE STRUCTURE OF SILK FIBROIN [J].
MARSH, RE ;
COREY, RB ;
PAULING, L .
BIOCHIMICA ET BIOPHYSICA ACTA, 1955, 16 (01) :1-34