Interesting and effective P,N-chelation of tetrasubstituted ferrocene ligands for palladium-catalyzed asymmetric allylic substitution

被引：133

作者：

Zhang, WB ^{[1
]}

Hirao, T ^{[1
]}

Ikeda, I ^{[1
]}

机构：

[1] OSAKA UNIV,FAC ENGN,DEPT APPL CHEM,SUITA,OSAKA 565,JAPAN

来源：

TETRAHEDRON LETTERS | 1996年 / 37卷 / 26期

关键词：

D O I：

10.1016/0040-4039(96)00899-4

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The complexation of 1,1'-bis(diphenylphosphino)-2,2'-bis(oxazolinyl)-ferrocene with palladium(II) in solution was studied and with this kind of P,N-chelating tetrasubstituted ferrocene compounds as chiral ligands, up to 99% ee was given to the palladium-catalyzed asymmetric allylic substitution of 1,3-diphenyl-2-propenyl acetate with sodium dimethyl malonate. Copyright (C) 1996 Elsevier Science Ltd

引用

页码：4545 / 4548

页数：4

共 26 条

[1] A NEW CLASS OF CHIRAL PHOSPHORUS CATALYST FOR ASYMMETRIC PALLADIUM-CATALYZED ALLYLIC SUBSTITUTION-REACTIONS
BRENCHLEY, G
MERIFIELD, E
WILLS, M
FEDOULOFF, M
[J]. TETRAHEDRON LETTERS, 1994, 35 (17) : 2791 - 2794
[2] MECHANISTIC AND SYNTHETIC STUDIES IN CATALYTIC ALLYLIC ALKYLATION WITH PALLADIUM COMPLEXES OF 1-(2-DIPHENYLPHOSPHINO-1-NAPHTHYL)ISOQUINOLINE
BROWN, JM
HULMES, DI
GUIRY, PJ
[J]. TETRAHEDRON, 1994, 50 (15) : 4493 - 4506
[3] ENANTIOSELECTIVE HOMOGENEOUS CATALYSIS INVOLVING TRANSITION-METAL ALLYL INTERMEDIATES
CONSIGLIO, G
WAYMOUTH, RM
[J]. CHEMICAL REVIEWS, 1989, 89 (01) : 257 - 276
[4] SULFIDES TETHERED TO OXAZOLINES - LIGANDS FOR ENANTIOSELECTIVE CATALYSIS
DAWSON, GJ
FROST, CG
MARTIN, CJ
WILLIAMS, JMJ
[J]. TETRAHEDRON LETTERS, 1993, 34 (48) : 7793 - 7796
[5] ENANTIOSELECTIVE SYNTHESIS OF SUCCINIC ACIDS AND GAMMA-LACTONES VIA PALLADIUM-CATALYZED ALLYLIC SUBSTITUTION-REACTIONS
DAWSON, GJ
WILLIAMS, JMJ
COOTE, SJ
[J]. TETRAHEDRON-ASYMMETRY, 1995, 6 (10) : 2535 - 2546
[6] SELECTIVITY IN PALLADIUM CATALYZED ALLYLIC SUBSTITUTION
FROST, CG
HOWARTH, J
WILLIAMS, JMJ
[J]. TETRAHEDRON-ASYMMETRY, 1992, 3 (09) : 1089 - 1122
[7] A NEW CHIRAL FERROCENYLPHOSPHINE LIGAND WITH C2 SYMMETRY - PREPARATION AND USE FOR PALLADIUM-CATALYZED ASYMMETRIC CROSS-COUPLING
HAYASHI, T
YAMAMOTO, A
HOJO, M
ITO, Y
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1989, (08) : 495 - 496
[8] MODIFICATION OF OPTICALLY-ACTIVE FERROCENYLPHOSPHINE LIGANDS FOR PALLADIUM-CATALYZED ASYMMETRIC ALLYLIC ALKYLATION
HAYASHI, T
YAMAMOTO, A
HAGIHARA, T
ITO, Y
[J]. TETRAHEDRON LETTERS, 1986, 27 (02) : 191 - 194
[9] ASYMMETRIC-SYNTHESIS CATALYZED BY CHIRAL FERROCENYLPHOSPHINE-TRANSITION METAL-COMPLEXES .8. NEW CHIRAL FERROCENYLPHOSPHINES WITH C2 SYMMETRY
HAYASHI, T
YAMAMOTO, A
HOJO, M
KISHI, K
ITO, Y
NISHIOKA, E
MIURA, H
YANAGI, K
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1989, 370 (1-3) : 129 - 139
[10] HAYASHI T, 1993, CATALYTIC ASYMMETRIC, P325

← 1 2 3 →