Selective oxidation of alcohols in the presence of an Os/O2system

被引：69

作者：

Döbler, C

Mehltretter, GM

Sundermeier, U

Eckert, M

Militzer, HC

Beller, M

机构：

[1] Univ Rostock eV, Inst Organ Katalyseforsch, IfOK, D-18055 Rostock, Germany

[2] Bayer AG, D-51368 Leverkusen, Germany

来源：

TETRAHEDRON LETTERS | 2001年 / 42卷 / 48期

关键词：

oxidation; alcohols; aldehydes; oxygen; osmium;

D O I：

10.1016/S0040-4039(01)01747-6

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The osmium-catalyzed oxidation of alcohols with molecular oxygen to give aldehydes in good to excellent yields has been developed. Best results are obtained by using a buffered two-phase system with a constant pH of 10.4. Under optimized reaction conditions a remarkable catalyst productivity (TON up to 16600) is observed. (C) 2001 Published by Elsevier Science Ltd.

引用

页码：8447 / 8449

页数：3

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