Chiral synthesis of the necic acid components, crobarbatic acid and integerrinecic acid lactone

被引：13

作者：

Honda, T

Ishikawa, F

Yamane, S

机构：

[1] Institute of Medicinal Chemistry, Hoshi University, Shinagawa-ku, Tokyo 142

来源：

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1 | 1996年 / 11期

关键词：

D O I：

10.1039/p19960001125

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Samarium(II) diiodide-promoted regioselective fragmentation of the gamma-halogeno esters 12 and 13 afforded the olefins 14 and 20, respectively, which were converted into the necic acid components, crobarbatic acid and a known advanced intermediate of integerrinecic acid lactone, of macropyrrolizidine alkaloids.

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页码：1125 / 1130

页数：6

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