Cycloaddition reactions of porphyrins

被引：64

作者：

Cavaleiro, JAS ^{[1
]}

Neves, MGPMS ^{[1
]}

Tomé, AC ^{[1
]}

机构：

[1] Univ Aveiro, Dept Chem, P-3810193 Aveiro, Portugal

来源：

ARKIVOC | 2003年

关键词：

porphyrins; chlorins; bacteriochlorins; isobacteriochlorins; naphthoporphyrins; pyrroloporphyrins; Diels-Alder reaction; 1,3-dipolar cycloaddition; 1,5-electrocyclization; carbenes; nitrenes;

D O I：

10.3998/ark.5550190.0004.e11

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Adequately substituted porphyrins can participate in pericyclic reactions as dienes, dienophiles, dipolarophiles and as 1,3-dipoles. They also show interesting dipolar 1,5-electrocyclizations and cheletropic reactions with carbenes. All these different types of reactivity have been exploited in order to synthesize new potential biologically active porphyrin derivatives, mainly chlorins and bacteriochlorins. This paper reviews the most recent works where porphyrins have participated in pericyclic reactions.

引用

页码：107 / 130

页数：24

共 64 条

[1] Hetero-Diels-Alder reactions of β-imino-meso-tetraphenylporphyrin derivatives:: a new approach to pyrido[2,3-b]porphyrins [J].