Sample stacking of fast-moving anions in capillary zone electrophoresis with pH-suppressed electroosmotic flow

被引：88

作者：

Quirino, JP ^{[1
]}

Terabe, S ^{[1
]}

机构：

[1] Himeji Inst Technol, Fac Sci, Kamigori, Hyogo 6781297, Japan

来源：

JOURNAL OF CHROMATOGRAPHY A | 1999年 / 850卷 / 1-2期

关键词：

sample stacking; field enhanced sample injection; injection methods; inorganic anions;

D O I：

10.1016/S0021-9673(99)00204-6

中图分类号：

Q5 [生物化学];

学科分类号：

071010 ; 081704 ;

摘要：

On-line sample concentration of fast moving inorganic anions by large volume sample stacking (LVSS) and field enhanced sample injection (FESI) with a water plug under acidic conditions is presented. Detection sensitivity enhancements were around 100 and 1000-fold for LVSS and FESI, respectively. However, reproducibility and linearity of response in the LVSS approach is superior compared to the FESI approach. (C) 1999 Elsevier Science B.V. All rights reserved.

引用

页码：339 / 344

页数：6

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