A highly active alkane dehydrogenation catalyst: Stabilization of dihydrido rhodium and iridium complexes by a P-C-P pincer-ligand

被引：302

作者：

Gupta, M

Hagen, C

Flesher, RJ

Kaska, WC

Jensen, CM

机构：

[1] UNIV CALIF SANTA BARBARA,DEPT CHEM,SANTA BARBARA,CA 93106

[2] UNIV HAWAII,DEPT CHEM,HONOLULU,HI 96822

来源：

CHEMICAL COMMUNICATIONS | 1996年 / 17期

关键词：

D O I：

10.1039/cc9960002083

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The novel P-C-P pincer complex, [IrH2{C6H3(CH(2)PBu(2)(t))(2)-2,6}] has long-term stability at 200 degrees C and catalyses the transfer dehydrogenation of cyclooctane to cyclooctene at the rate of 12 turnovers min(-1).

引用

页码：2083 / 2084

页数：2

共 22 条

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