Saturated and unsaturated anteiso-C19 acids in the seed lipids from Hesperopeuce mertensiana (Pinaceae)

被引：29

作者：

Destaillats, F

Wolff, RL

Angers, P

机构：

[1] Univ Laval, Dept Food Sci & Nutr, St Foy, PQ G1K 7P4, Canada

[2] Univ Laval, Ctr Dairy Res, STELA, St Foy, PQ G1K 7P4, Canada

[3] Univ Bordeaux 1, Inst Sci & Tech Aliments Bordeaux, F-33405 Talence, France

来源：

LIPIDS | 2002年 / 37卷 / 03期

基金：

加拿大自然科学与工程研究理事会;

关键词：

D O I：

10.1007/s11745-002-0898-y

中图分类号：

Q5 [生物化学]; Q7 [分子生物学];

学科分类号：

071010 ; 081704 ;

摘要：

Minor uncommon FA from Hesperopeuce mertensiana (a gymnosperm species of the Pinaceae family) seed oil were characterized through a combination of silver ion TLC of their FAME, and GLC coupled with MS of their picolinyl derivatives. These uncommon components have the structures 16-methyloctaclecanoic (anteiso-19:0), 16-methyl-cis-9-octaclecenoic (anteiso-19:1), and 16-methyl-cis-9,cis-12-octadecadienoic (anteiso-19:2) acids. These branched C-19 acids were identified earlier in the wood of Picea abies, which would indicate that such acids could be widespread, though minor, components of Pinaceae lipids.

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页码：325 / 328

页数：4

相关论文

共 10 条

[1] One-step methodology for the synthesis of FA picolinyl esters from intact lipids [J].

Destaillats, F ;

Angers, P .

JOURNAL OF THE AMERICAN OIL CHEMISTS SOCIETY, 2002, 79 (03) :253-256

[2] NEW POLYENOIC FATTY-ACIDS IN NORWAY SPRUCE WOOD [J].

EKMAN, R .

PHYTOCHEMISTRY, 1980, 19 (01) :147-148

[3] PICOLINYL ESTERS AS DERIVATIVES FOR THE STRUCTURAL DETERMINATION OF LONG-CHAIN BRANCHED AND UNSATURATED FATTY-ACIDS [J].

HARVEY, DJ .

BIOMEDICAL MASS SPECTROMETRY, 1982, 9 (01) :33-38

[4] LEAF LIPIDS OF SOME CONIFER SPECIES [J].

JAMIESON, GR ;

REID, EH .

PHYTOCHEMISTRY, 1972, 11 (01) :269-&

[5] CIS-5-POLYENOIC ACIDS IN LARIX-LEPTOLEPIS SEED OIL [J].

PLATTNER, RD ;

SPENCER, GF ;

KLEIMAN, R .

LIPIDS, 1975, 10 (07) :413-416

[6] Abietoid seed fatty acid compositions -: A review of the genera Abies, Cedrus, Hesperopeuce, Keteleeria, Pseudolarix, and Tsuga and preliminary inferences on the taxonomy of Pinaceae [J].

Wolff, RL ;

Lavialle, O ;

Pédrono, F ;

Pasquier, E ;

Destaillats, F ;

Marpeau, AM ;

Angers, P ;

Aitzetmüller, K .

LIPIDS, 2002, 37 (01) :17-26

[7] Fatty acid composition of Pinaceae as taxonomic markers [J].

Wolff, RL ;

Lavialle, O ;

Pédrono, F ;

Pasquier, E ;

Deluc, LG ;

Marpeau, AM ;

Aitzetmüller, K .

LIPIDS, 2001, 36 (05) :439-451

[8] α-linolenic acid and its Δ5-desaturation product, coniferonic acid, in the seed lipids of Tsuga and Hesperopeuce as a taxonomic means to differentiate the two genera [J].

Wolff, RL ;

Destaillats, F ;

Angers, P .

LIPIDS, 2001, 36 (02) :211-212

[9] The unusual occurrence of 14-methylhexadecanoic acid in pinaceae seed oils among plants [J].

Wolff, RL ;

Christie, WW ;

Coakley, D .

LIPIDS, 1997, 32 (09) :971-973

[10] General characteristics of Pinus spp. seed fatty acid compositions, and importance of Δ5-olefinic acids in the taxonomy and phylogeny of the genus [J].

Wolff, RL ;

Pédrono, F ;

Pasquier, E ;

Marpeau, AM .

LIPIDS, 2000, 35 (01) :1-22