The use of high energy radiation as a probe for the characterisation of polyester melamine coating matrices

被引：2

作者：

Gamage, NJW

Hill, DJT

Lukey, CA ^{[1
]}

Pomery, PJ

机构：

[1] Univ Wollongong, Steel Inst, Wollongong, NSW 2522, Australia

[2] Univ Queensland, Dept Chem, Polymer Mat & Radiat Grp, Brisbane, Qld 4072, Australia

来源：

RADIATION PHYSICS AND CHEMISTRY | 2004年 / 69卷 / 06期

关键词：

radiolysis; polyester/melamines; ESR; degradation; characterisation;

D O I：

10.1016/j.radphyschem.2003.10.003

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

ESR spectroscopy was used to study the high energy (gamma) radiolysis, at low temperature in vacuum, of a series of polyester-melamine clearcoats. The results were interpreted in terms of the formation of unstable free radical intermediates. G values for free radical formation were used as a measure of the radiation stability of the crosslinked matrix, and the structural characteristics of the polymer were inferred from the nature of the free radicals generated. (C) 2003 Elsevier Ltd. All rights reserved.

引用

页码：487 / 493

页数：7

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