Synthesis and structure of a linked-bis(amidate) ligand and some complexes with titanium

被引：28

作者：

Giesbrecht, GR

Shafir, A

Arnold, J ^{[1
]}

机构：

[1] Univ Calif Berkeley, Dept Chem, Berkeley, CA 94720 USA

[2] Lawrence Berkeley Natl Lab, Div Chem Sci, Berkeley, CA 94720 USA

来源：

INORGANIC CHEMISTRY | 2001年 / 40卷 / 23期

关键词：

D O I：

10.1021/ic010533o

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The synthesis of a new ligand system in which two amides are coupled via a rigid phenylene spacer is readily accomplished in a high-yield, single-step reaction. The dilithio salt (NO)2Li2(THF)x reacts with Ti(NR2)4 (R = Me, Et) to yield the titanium amides [(NO)2Ti(NR2)2]2. The latter react with excess Me3SiCl to produce the dichloride (NO)2TiCl2, which was also obtained by the reaction of [(NO)2Ti(NMe2)2]2 with TiCl4(THF)2 in refluxing toluene, and in a lower-yielding route, by salt metathesis between the dilithio salt and TiCl4(THF)2.

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页码：6069 / 6072

页数：4

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