A novel two-phase oxidative coupling of 2-naphthols suspended in aqueous Fe3+ solutions

被引：113

作者：

Ding, KL ^{[1
]}

Wang, Y ^{[1
]}

Zhang, LJ ^{[1
]}

Wu, YJ ^{[1
]}

Matsuura, T ^{[1
]}

机构：

[1] RYUKOKU UNIV,FAC SCI & TECHNOL,DEPT CHEM MAT,OTSU,SHIGA 52021,JAPAN

来源：

TETRAHEDRON | 1996年 / 52卷 / 03期

关键词：

D O I：

10.1016/0040-4020(95)00941-8

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The oxidative coupling of 2-naphthols suspended in aqueous Fe3+ solutions gives corresponding 1,1'-bi-2-naphthols in the yields of 91-95%. This reaction can be also effectively applied to the large-scale synthesis of 1,1' -bi-2-naphthol. It was suggested that the oxidation occurred at the surface of the crystalline 2-naphthols via a solid-liquid process.

引用

页码：1005 / 1010

页数：6

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