Hexa-μ-chloro-μ4-oxo-tetrakis[(4,5-dihydro-2-methyl-1,2-thiazole-κN)-copper(II)]

被引:8
作者
Bolos, CA
Christidis, PC [1 ]
机构
[1] Aristotelian Univ Thessaloniki, Dept Phys, Appl Phys Lab, GR-54006 Thessaloniki, Greece
[2] Aristotelian Univ Thessaloniki, Dept Chem, Inorgan Chem Lab, GR-54006 Thessaloniki, Greece
关键词
D O I
10.1107/S0108270101016870
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The title compound, [Cu4Cl6O(C4H7NS)(4)], was obtained by the reaction of CuCl2.2H(2)O with 2-methyl-2-thiazoline in methanol. The complex has twofold crystallographic symmetry and contains a tetrahedron of four Cu-II atoms coordinating a central mu(4)-O atom, with the six edges of the tetrahedron bridged by Cl atoms. Distance ranges are Cu-O 1.917 (4)-1.920 (4) and Cu-Cl 2.370 (2)-2.445 (2) Angstrom.
引用
收藏
页码:M29 / M30
页数:2
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