Merging homogeneous catalysis with biocatalysis; papain as hydrogenation catalyst

被引:70
作者
Panella, L
Broos, J
Jin, JF
Fraaije, MW
Janssen, DB
Jeronimus-Stratingh, M
Feringa, BL
Minnaard, AJ
de Vries, JG
机构
[1] Univ Groningen, Dept Organ & Mol Inorgan Chem, NL-9747 AG Groningen, Netherlands
[2] Univ Groningen, Dept Biochem, NL-9747 AG Groningen, Netherlands
[3] Univ Groningen, Fac Ctr Mass Spectrometry, NL-9713 AV Groningen, Netherlands
[4] DSM Res & Patents, NL-6160 MD Geleen, Netherlands
关键词
D O I
10.1039/b512138h
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Papain, modified at Cys-25 with a monodentate phosphite ligand and complexed with Rh(COD)(2)BF4, is an active catalyst in the hydrogenation of methyl 2-acetamidoacrylate.
引用
收藏
页码:5656 / 5658
页数:3
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