Highly efficient pure-white-light-emitting diodes from a single polymer: Polyfluorene with naphthalimide moieties

被引:203
作者
Tu, GL [1 ]
Mei, CY [1 ]
Zhou, QG [1 ]
Cheng, YX [1 ]
Geng, YH [1 ]
Wang, LX [1 ]
Ma, DG [1 ]
Jing, XB [1 ]
Wang, FS [1 ]
机构
[1] Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Polymer Phys & Chem, Changchun 130022, Peoples R China
关键词
D O I
10.1002/adfm.200500028
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Light-emitting diodes exhibiting efficient pure-white-light electroluminescence have been successfully developed by using a single polymer: polyfluorene derivatives with 1,8-naphthalimide chromophores chemically doped onto the polyfluorene backbones. By adjusting the emission wavelength of the 1,8-naphthalimide components and optimizing the relative content of 1,8-naphthalimide derivatives in the resulting polymers, white-light electroluminescence from a single polymer, as opposed to a polymer blend, has been obtained in a device with a configuration of indium tin oxide/poly(3,4-ethyleiledioxythiophene)(50 nm)/polymer(80 nm)/Ca(10 nm)/Al(100 nm). The device exhibits Commission Internationale de I'Eclairage coordinates of (0.32,0.36), a maximum brightness of 11900 cd m(-2), a current efficiency of 3.8 cd A(-1), a power efficiency of 2.0 lm W-1. an external quantum efficiency of 1.50 %, and quite stable color coordinates at different driving voltages, even at high luminances of over 5000 cd m(-2).
引用
收藏
页码:101 / 106
页数:6
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