Studies directed towards the synthesis of miharamycin B.

被引：17

作者：

Czernecki, S

Franco, S

Horns, S

Valery, JM

机构：

[1] Laboratoire de Chimie des Glucides, Univ. Pierre et Marie Curie, 75005 Paris

来源：

TETRAHEDRON LETTERS | 1996年 / 37卷 / 23期

关键词：

miharamycin; complex nucleoside antibiotics;

D O I：

10.1016/0040-4039(96)00768-X

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The northern part of Miharamycin B which differs from the natural product by the absence of a 2-carbon branched chain in the sugar moiety, was prepared by a sequence of selective transformations from methyl 2,3,4-tri-O-benzyl-alpha-D-gluco-hexodialdo-1,5-pyranoside 3. The key step is a regioselective glycosylation of 2-aminopurine. (C) 1996 Published by Elsevier Science Ltd.

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收藏

页码：4003 / 4006

页数：4

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