Expanded graphite as a support for Ni/carbon composites

被引：46

作者：

Afanasov, I. M. ^{[1
]}

Shornikova, O. N. ^{[1
]}

Avdeev, V. V. ^{[1
]}

Lebedev, O. I. ^{[2
]}

Van Tendeloo, G. ^{[2
]}

Matveev, A. T. ^{[3
]}

机构：

[1] Moscow MV Lomonosov State Univ, Dept Chem, Moscow 119991, Russia

[2] Univ Antwerp, EMAT, B-2020 Antwerp, Belgium

[3] Inst New Carbon Mat, Moscow 119991, Russia

来源：

CARBON | 2009年 / 47卷 / 02期

关键词：

CARBON NANOTUBES; METHANE DECOMPOSITION; HYDROGEN STORAGE; ACTIVATED CARBON; NI CATALYSTS; NICKEL; ELECTRODES; NANOPARTICLES; PERFORMANCE; NANOFIBERS;

D O I：

10.1016/j.carbon.2008.10.034

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Expanded graphite decorated with nickel oxide particles (EG(NiO)) has been synthesized through electrochemical oxidation of natural graphite in an aqueous nickel nitrate solution followed by a heat treatment. EG(NiO) was used to prepare nickel/carbon composites using two techniques: (a) hydrogen reduction of nickel oxide particles loaded on the expanded graphite surface and (b) pyrolysis of coal tar pitch-impregnated EG(NiO) blocks. The EG(NiO) as well as the nickel/carbon composites have been characterized by X-ray diffraction, scanning and transmission electron microscopy, energy dispersive X-ray spectroscopy and selected area electron diffraction. (C) 2008 Elsevier Ltd. All rights reserved.

引用

页码：513 / 518

页数：6

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