Network morphology of polymer stabilized liquid crystal

被引:87
作者
Dierking, I [1 ]
Kosbar, LL [1 ]
AfzaliArdakani, A [1 ]
Lowe, AC [1 ]
Held, GA [1 ]
机构
[1] IBM CORP,THOMAS J WATSON RES CTR,YORKTOWN HTS,NY 10598
关键词
D O I
10.1063/1.120087
中图分类号
O59 [应用物理学];
学科分类号
摘要
Monomer solubility is identified as the primary fatter determining network morphology in polymer stabilized cholesteric liquid crystal textures. Poorly soluble monomers form coarse structures composed of discrete, oblong grains, whereas soluble monomers yield smooth, continuous polymer networks. A crossover from smooth to grainy structure is observed as a function of monomer concentration. The grainy structure results from precipitation polymerization and the observed behavior is well described by the Flory-Huggins theory of polymer solubility. (C) 1997 American Institute of Physics. [S0003-6951(97)01143-1].
引用
收藏
页码:2454 / 2456
页数:3
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