Terminology of metal-organic frameworks and coordination polymers (IUPAC Recommendations 2013)

被引：1004

作者：

Batten, Stuart R. ^{[1
]}

Champness, Neil R. ^{[2
]}

Chen, Xiao-Ming ^{[3
]}

Garcia-Martinez, Javier ^{[4
]}

Kitagawa, Susumu ^{[5
]}

Ohrstrom, Lars ^{[6
]}

O'Keeffe, Michael ^{[7
]}

Suh, Myunghyun Paik ^{[8
]}

Reedijk, Jan ^{[9
]}

机构：

[1] Monash Univ, Sch Chem, Clayton, Vic 3800, Australia

[2] Univ Nottingham, Sch Chem, Nottingham NG7 2RD, England

[3] Sun Yat Sen Univ, Sch Chem & Chem Engn, Guangzhou 510275, Guangdong, Peoples R China

[4] Univ Alicante, Dept Quim Inorgan, E-03690 Alicante, Spain

[5] Kyoto Univ, Dept Synthet Chem & Biol Chem, Nishikyo Ku, Kyoto 6158510, Japan

[6] Chalmers Univ Technol, Dept Chem & Biol Engn, SE-41296 Gothenburg, Sweden

[7] Arizona State Univ, Dept Chem & Biochem, Tempe, AZ 85287 USA

[8] Seoul Natl Univ, Dept Chem, Seoul 151747, South Korea

[9] Leiden Univ, Leiden Inst Chem, NL-2300 RA Leiden, Netherlands

来源：

PURE AND APPLIED CHEMISTRY | 2013年 / 85卷 / 08期

关键词：

coordination chemistry; coordination networks; coordination polymers; inorganic chemistry; IUPAC Inorganic Chemistry Division; materials chemistry; metal complexes; metal-organic frameworks (MOFs); nanostructured materials; polymers; NETWORKS; TERMS;

D O I：

10.1351/PAC-REC-12-11-20

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A set of terms, definitions, and recommendations is provided for use in the classification of coordination polymers, networks, and metal-organic frameworks (MOFs). A hierarchical terminology is recommended in which the most general term is coordination polymer. Coordination networks are a subset of coordination polymers and MOFs a further subset of coordination networks. One of the criteria an MOF needs to fulfill is that it contains potential voids, but no physical measurements of porosity or other properties are demanded per se. The use of topology and topology descriptors to enhance the description of crystal structures of MOFs and 3D-coordination polymers is furthermore strongly recommended.

引用

页码：1715 / 1724

页数：10

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