Self-assembly of an organometallic silver(I) 1D architecture supported by three different types of bonding interactions

被引：31

作者：

Reger, DL ^{[1
]}

Semeniuc, RF ^{[1
]}

Smith, MD ^{[1
]}

机构：

[1] Univ S Carolina, Dept Chem & Biochem, Columbia, SC 29208 USA

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2002年 / 5卷 / 04期

基金：

美国国家科学基金会;

关键词：

ID coordination polymer; silver(I); tris(pyrazolylmethane ligand; eta(2)-arenel;

D O I：

10.1016/S1387-7003(02)00374-X

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The new ligand o-C6H4[CH2OCH2C(3-Phpz)(3)](2) (pz=pyrazolyl ring) reacts with AgBF4 to yield the coordination polymer {o-C6H4[CH2OCH2C(3-Phpz)(3)](2)Ag-2(BF4)(2)}(n). The organometallic supramolecular architecture contains two different types of silver(I) cations arranged in bimetallic units forming a 1D coordination polymer. The bimetallic units show three different types of bridging interactions, including a mu-kappa(1), kappa(2)-tris(3-Ph-pyrazolyl)methane unit, a silver eta(2)-bonded to it phenyl group and pi-pi stacking interactions. (C) 2002 Published by Elsevier Science B.V.

引用

页码：278 / 282

页数：5

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