Mean-square amplitudes of vibration of the metal atom in iron-organometallics

被引:11
作者
Herber, RH [1 ]
Nowik, I [1 ]
机构
[1] Hebrew Univ Jerusalem, Racah Inst Phys, IL-91904 Jerusalem, Israel
来源
HYPERFINE INTERACTIONS | 2001年 / 136卷 / 3-8期
关键词
ferrocene; motional anisotropy; Gol'danskii-Karyagin effect;
D O I
10.1023/A:1020525311379
中图分类号
O64 [物理化学(理论化学)、化学物理学]; O56 [分子物理学、原子物理学];
学科分类号
070203 ; 070304 ; 081704 ; 1406 ;
摘要
Fe-57 Mossbauer effect data for ferrocene over the temperature range 90 less than or equal to T < 370 K have been analyzed in detail to yield the mean-square amplitudes of vibration of the metal atom in this solid. The presence of a large anisotropy in this motion at high temperatures is readily extracted from the data.
引用
收藏
页码:699 / 703
页数:5
相关论文
共 10 条
[1]   Rigid-body disorder models for the high-temperature phase of ferrocene [J].
Brock, CP ;
Fu, YG .
ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1997, 53 :928-938
[2]   THE THERMODYNAMIC PROPERTIES OF FERROCENE .1. THE LOW-TEMPERATURE TRANSITION IN FERROCENE CRYSTALS [J].
EDWARDS, JW ;
KINGTON, GL ;
MASON, R .
TRANSACTIONS OF THE FARADAY SOCIETY, 1960, 56 (05) :660-667
[3]  
GOLDANSKII VI, 1968, CHEM APPLICATIONS MO, P103
[4]   Atomic and molecular dynamics in organometallics: anisotropy of iron atom motion in ferrocene [J].
Herber, RH ;
Nowik, I .
SOLID STATE SCIENCES, 2002, 4 (05) :691-694
[5]  
HERBER RH, 1984, CHEM MOSSBAUER SPECT, P199
[6]   Comment on "Mossbauer effect study of filled antimonide skutterudites" [J].
Rechenberg, HR .
PHYSICAL REVIEW B, 2000, 62 (10) :6827-6828
[7]   STRUCTURE OF TRICLINIC FERROCENE AT 101-K, 123-K AND 148-K [J].
SEILER, P ;
DUNITZ, JD .
ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1979, 35 (SEP) :2020-2032
[8]   NEW INTERPRETATION OF THE DISORDERED CRYSTAL-STRUCTURE OF FERROCENE [J].
SEILER, P ;
DUNITZ, JD .
ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1979, 35 (MAY) :1068-1074
[9]   LOW-TEMPERATURE CRYSTALLIZATION OF ORTHORHOMBIC FERROCENE - STRUCTURE-ANALYSIS AT 98-K [J].
SEILER, P ;
DUNITZ, JD .
ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1982, 38 (JUN) :1741-1745
[10]  
SHENOY GK, 1974, MOSSBAUER EFFECT MET, V9, P277