A mixed valent iron oxycarbonate closely related to the n=3 member of the RP series Sr4Fe3-x(CO3)xO10-4x-δ

被引：23

作者：

Bréard, Y

Michel, C

Hervieu, M

Raveau, B

机构：

[1] ISMRA, CNRS, UMR6508, Lab CRISMAT, F-14050 Caen, France

[2] Univ Caen, F-14050 Caen, France

来源：

JOURNAL OF MATERIALS CHEMISTRY | 2000年 / 10卷 / 05期

关键词：

D O I：

10.1039/b000814l

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A new oxycarbonate Sr4Fe2.6O8.2(CO3)(0.4) closely related to the n=3 member of the Ruddlesden-Popper family has been synthesized; it exhibits the presence of Fe3+ and Fe4+ in low spin configuration and a magnetic transition at 35 K.

引用

页码：1043 / 1045

页数：3

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