A study of nitrobenzene hydrogenation over palladium/carbon catalysts

被引：82

作者：

Gelder, EA

Jackson, SD ^{[1
]}

Lok, CM

机构：

[1] Univ Glasgow, Dept Chem, Glasgow G12 8QQ, Lanark, Scotland

[2] Synetix, Billingham TS23 1LB, Cleveland, England

来源：

CATALYSIS LETTERS | 2002年 / 84卷 / 3-4期

基金：

英国工程与自然科学研究理事会;

关键词：

palladium; nitrobenzene; hydrogenation; carbon; aniline; particle size effect;

D O I：

10.1023/A:1021432104496

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The hydrogenation of nitrobenzene has been studied over three palladium/carbon catalysts using methanol and isopropanol as solvents. A solvent and palladium particle size effect have both been observed, with the nature of the particle size effect dependent upon the solvent. This may be related to a change in the rate-determining step.

引用

页码：205 / 208

页数：4

共 12 条

[1] Study on silica supported Cu-Cr-Mo nitrobenzene hydrogenation catalysts [J].