Multifunctional DyIII4 Cluster Exhibiting White-Emitting, Ferroelectric and Single-Molecule Magnet Behavior

被引：100

作者：

Guo, Peng-Hu ^{[1
]}

Liu, Jun-Liang ^{[1
]}

Jia, Jian-Hua ^{[1
]}

Wang, Jing ^{[1
]}

Guo, Fu-Sheng ^{[1
]}

Chen, Yan-Cong ^{[1
]}

Lin, Wei-Quan ^{[1
]}

Leng, Ji-Dong ^{[1
]}

Bao, Ding-Hua ^{[2
]}

Zhang, Xu-Dong ^{[3
]}

Luo, Jun-Hua ^{[3
]}

Tong, Ming-Liang ^{[1
]}

机构：

[1] Sun Yat Sen Univ, Sch Chem & Chem Engn, MOE Key Lab Bioinorgan & Synthet Chem, State Key Lab Optoelect Mat & Technol, Guangzhou 510275, Guangdong, Peoples R China

[2] Sun Yat Sen Univ, Sch Phys & Engn, MOE Key Lab Bioinorgan & Synthet Chem, State Key Lab Optoelect Mat & Technol, Guangzhou 510275, Guangdong, Peoples R China

[3] Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Peoples R China

来源：

CHEMISTRY-A EUROPEAN JOURNAL | 2013年 / 19卷 / 27期

关键词：

chirality; dysprosium; ferroelectric; lanthanides; LEDs; single-molecule magnet; white-light emitting; METAL-ORGANIC FRAMEWORK; COORDINATION POLYMER; SPIN STATES; COMPLEXES; LIGHT; TRANSFORMATION; TRANSITION; ANISOTROPY; RESOLUTION; EMISSION;

D O I：

10.1002/chem.201300299

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Multifunctional material: A remarkable case of a single-molecule magnet that demonstrates white-light emission and ferroelectricity was observed in a butterfly-shaped chiral DyIII4 cluster, [Dy 4(μ-bpt)4(μ3-OH)2(μ-OMe) 2(NO3)4]×3 MeOH (bpt=3,5-bis(pyridin-2- yl)-1,2,4-trizolate, see figure). Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：8769 / 8773

页数：5

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