Recent developments in and applications of resonance ionization mass spectrometry

被引：55

作者：

Wendt, K ^{[1
]}

Blaum, K

Bushaw, BA

Grüning, C

Horn, R

Huber, G

Kratz, JV

Kunz, P

Müller, P

Nörtershäuser, W

Nunnemann, M

Passler, G

Schmitt, A

Trautmann, N

Waldek, A

机构：

[1] Johannes Gutenberg Univ Mainz, Inst Phys, D-55099 Mainz, Germany

[2] Johannes Gutenberg Univ Mainz, Inst Kernchem, D-55099 Mainz, Germany

[3] Pacific NW Lab, Richland, WA 99352 USA

来源：

FRESENIUS JOURNAL OF ANALYTICAL CHEMISTRY | 1999年 / 364卷 / 05期

关键词：

D O I：

10.1007/s002160051370

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

Resonance Ionization Mass Spectrometry (RIMS) has nowadays reached the status of a routine method for sensitive and selective ultratrace determination of long-lived radioactive isotopes in environmental, biomedical and technical samples. It provides high isobaric suppression, high to ultra-high isotopic selectivity and good overall efficiency. Experimental detection limits are as low as 10(6) atoms per sample and permit the fast and sensitive determination of ultratrace amounts of radiotoxic contaminations. Experimental arrangements for the detection of different radiotoxic isotopes, e.g. Pu236-244, Sr-89,Sr-90 and Tc-99 in environmental samples are described, and the application of RIMS to the ultrarare long-lived radioisotope Ca-41 for cosmochemical, radiodating and medical purposes are presented.

引用

页码：471 / 477

页数：7

共 22 条

[1] Properties and performance of a quadrupole mass filter used for resonance ionization mass spectrometry [J].

Blaum, K ;

Geppert, C ;

Müller, P ;

Nörtershäuser, W ;

Otten, EW ;

Schmitt, A ;

Trautmann, N ;

Wendt, K ;

Bushaw, BA .

INTERNATIONAL JOURNAL OF MASS SPECTROMETRY, 1998, 181 :67-87

[2]

Blaum K, 1998, AIP CONF PROC, V454, P275, DOI 10.1063/1.57159

[3] Lineshapes and optical selectivity in high-resolution double-resonance ionization mass spectrometry [J].

Bushaw, BA ;

Nörtershäuser, W ;

Wendt, K .

SPECTROCHIMICA ACTA PART B-ATOMIC SPECTROSCOPY, 1999, 54 (02) :321-332

[4] LASER-ENHANCED ELECTRON-IMPACT IONIZATION SPECTROSCOPY [J].

BUSHAW, BA ;

CANNON, BD ;

GERKE, GK ;

WHITAKER, TJ .

OPTICS LETTERS, 1986, 11 (07) :422-424

[5]

BUSHAW BA, 1989, PROG ANAL SPECTROSC, V12, P247

[6] Determination of the first ionization potential of nine actinide elements by resonance ionization mass spectroscopy (RIMS) [J].

Erdmann, N ;

Nunnemann, M ;

Eberhardt, K ;

Herrmann, G ;

Huber, G ;

Kohler, S ;

Kratz, JV ;

Passler, G ;

Peterson, JR ;

Trautmann, N ;

Waldek, A .

JOURNAL OF ALLOYS AND COMPOUNDS, 1998, 271 :837-840

[7]

Grüning C, 1998, AIP CONF PROC, V454, P285, DOI 10.1063/1.57161

[8]

HURST GS, 1998, PRINCIPLES APPL RESO

[9]

KLUGE HJ, 1994, FRESEN J ANAL CHEM, V350, P78

[10] Determination of the first ionization potential of actinide elements by resonance ionization mass spectroscopy [J].

Kohler, S ;

Deissenberger, R ;

Eberhardt, K ;

Erdmann, N ;

Herrmann, G ;

Huber, G ;

Kratz, JV ;

Nunnemann, M ;

Passler, G ;

Rao, PM ;

Riegel, J ;

Trautmann, N ;

Wendt, K .

SPECTROCHIMICA ACTA PART B-ATOMIC SPECTROSCOPY, 1997, 52 (06) :717-726

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