Self-assembly of hyperbranched spheres

被引：46

作者：

Huck, WTS ^{[1
]}

vanVeggel, FCJM ^{[1
]}

Reinhoudt, DN ^{[1
]}

机构：

[1] UNIV TWENTE, LAB SUPRAMOL CHEM & TECHNOL, NL-7500 AE ENSCHEDE, NETHERLANDS

来源：

JOURNAL OF MATERIALS CHEMISTRY | 1997年 / 7卷 / 07期

关键词：

D O I：

10.1039/a608577f

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A new type of building block with two coordinatively unsaturated palladium centres has been described that self-assembles in nitromethane solution and disassembles when acetonitrile is added. The resulting hyperbranched, organopalladium spheres have a remarkably narrow size distribution as was evidenced by light-scattering, AFM and TEM measurements. Variation of the structure of the building blocks showed the possibility to vary the size of the self-assembled spheres between 100 and 400 nm.

引用

页码：1213 / 1219

页数：7

共 18 条

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