Artificial Enzyme Catalysis Controlled and Driven by Light

被引：38

作者：

Knoer, Guenther ^{[1
]}

机构：

[1] Johannes Kepler Univ Linz, Inst Anorgan Chem, A-4040 Linz, Austria

来源：

CHEMISTRY-A EUROPEAN JOURNAL | 2009年 / 15卷 / 03期

关键词：

artificial photosynthesis; bioinorganic chemistry; coordination chemistry; enzyme catalysis; photochemistry; PHOTOINDUCED ELECTRON-TRANSFER; PROTON-TRANSFER CATALYSIS; O BOND FORMATION; 2-ELECTRON REDUCTION; MALATE-DEHYDROGENASE; SPIN STATES; CHEMISTRY; PHOTOCHEMISTRY; PHOTOCONTROL; EFFICIENCY;

D O I：

10.1002/chem.200801179

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Bio-inspired chemistry based on photoresponsive molecules is a rapidly developing new strategy to mimic the function of various biological systems. The interaction of electromagnetic radiation with molecular systems is ideally suited for the control and powering of dynamic processes at the speed of light. Besides typical applications in artificial photosynthesis, many other aspects, such as the catalytic turnover of substrates or the controlled release or uptake of small bioactive molecules. are readily verified with light-driven model systems. ne potential of this novel approach in biomimetic chemistry is briefly explored in this concept article.

引用

页码：568 / 578

页数：11

共 120 条

[1] (Salen)Mn(III)-catalyzed epoxidation reaction as a multichannel process with different spin states. Electronic tuning of asymmetric catalysis: A theoretical study [J].