Dynamic relaxation characteristics of Matrimid® polyimide

The dynamic relaxation characteristics of Matrimid (R) (BTDA-DAPI) polyimide have been investigated using dynamic mechanical and dielectric methods. Matrimid exhibits three motional processes with increasing temperature: two sub-glass relaxations (gamma and beta transitions), and the glass-rubber (alpha) transition. The low-temperature gamma transition is purely non-cooperative, and displays an identical time-temperature response to both the dynamic mechanical and the dielectric probes with a corresponding activation energy, E-A = 43 kJ/mol. The beta sub-glass transition shows a more cooperative character as assessed via the Starkweather method. Comparison of dynamic mechanical and dielectric data for the beta process suggests that the dynamic mechanical test (E-A = 156 kJ/mol) is sensitive to a broader, more strongly correlated range of sub-glass motions as compared to the dielectric probe (E-A = 99 kJ/mol). Time-temperature superposition was used to establish mechanical master curves across the glass-rubber (alpha) relaxation, and these data could be described using the Kohlrausch-Williams-Watts function with an exponent value, beta(KWW) = 0.34. The corresponding shift factors were used as the basis of a cooperativity plot for the determination of dynamic fragility. The relation between fragility index (m = 115) and beta(KWW) for the Matrimid polyimide was in good agreement with the wide correlation reported in the literature. (C) 2008 Elsevier Ltd. All rights reserved.