Reactions of dilithiobutadienes with monochlorosilanes: Observation of facile loss of organic groups from silicon

被引：45

作者：

Hudrlik, PF ^{[1
]}

Dai, DH ^{[1
]}

Hudrlik, AM ^{[1
]}

机构：

[1] Howard Univ, Dept Chem, Washington, DC 20059 USA

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2006年 / 691卷 / 06期

基金：

美国国家科学基金会;

关键词：

silole; chlorosilane; dilithiobutadiene; organosilicon; pentacoordinate silicon;

D O I：

10.1016/j.jorganchem.2005.11.068

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Reactions of 1,4-dilithiobutadieties (from 1,4-diiodo-1,2,3,4-tetraethylbutidiene (1) and 2,2'-dibromobiphenyl (7) with t-BuLi) with Me3SiCl gave siloles (3 and 9a) as the major products. No evidence for a disilylated butadiene was obtained. Use of higher molecular weight chlorosilanes ((allyl)Me2SiCl, BnMe2SiCl, and PhMe2SiCl) with dibromide 7 gave dimethylsilole 9a and a silane (10a, 10b, or 10c) resulting from trapping of the organic group by the chlorosilane. (c) 2005 Elsevier B.V. All rights reserved.

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页码：1257 / 1264

页数：8

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