Tribenzosubporphines: Synthesis and characterization

被引：198

作者：

Inokuma, Y

Kwon, JH

Ahn, TK

Yoo, MC

Kim, D ^{[1
]}

Osuka, A

机构：

[1] Yonsei Univ, Ctr Ultrfast Opt Characterist Contro, Seoul 120749, South Korea

[2] Yonsei Univ, Dept Chem, Seoul 120749, South Korea

[3] Kyoto Univ, Grad Sch Sci, Dept Chem, Kyoto 6068502, Japan

[4] Japan Sci & Technol Agcy, CREST, Sakyo Ku, Kyoto 6068502, Japan

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2006年 / 45卷 / 06期

关键词：

aromaticity; boron; macrocycles; porphyrinoids; template synthesis;

D O I：

10.1002/anie.200503426

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Figure Presented) Keeping it in the family: A one-pot condensation with a boric acid template leads to the synthesis of subporphineboron(III) complexes (see example; B green, O red, N blue, C turquoise, H white), ring-contracted congeners of porphyrins. Facile axial ligand exchange reactions provide alkoxy- and carboxy-coordinated subporphyrins, which have bowl-shaped structures with a bowl depth that depends on the axial group. © 2006 Wiley-VCH Verlag GmbH & Co. KGaA.

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页码：961 / 964

页数：4

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