Tl1 three-dimensional coordination polymer involving tetranuclear cubic cage nodes, [Tl4(μ8-SB)2]n{H2SB=4-[(4-hydroxyphenyl) sulfonyl]-1-benzenol

被引：47

作者：

Askarinejad, A ^{[1
]}

Morsali, A ^{[1
]}

机构：

[1] Tarbiat Modares Univ, Sch Sci, Dept Chem, Tehran, Iran

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2006年 / 9卷 / 02期

关键词：

thallium; 4-[(4-hydroxyphenyl)sulfonyl]-1-benzenol; lone pair; 3D coordination polymer;

D O I：

10.1016/j.inoche.2005.10.022

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The single crystal X-ray analysis of a novel Tl-1 coordination polymer of 4-[(4-hydroxyphenyl)sulfonyl]-benzenol (H2SB) ligand shows that the complex is a three-dimensional polymer as a result of bridging "SB2-" ligands with basic repeating [Tl-4(mu(8)-SB)(2)] units. There are four thallium. atoms with different coordination spheres in the cubic cage. These thallium atoms contain irregular coordination sphere with stereo-chemically active lone pair and thallium-thallium interactions, Tl(1)O-4, Tl(2)O4Tl2, Tl(3)O4Tl and TI(4)O3Tl. (c) 2005 Elsevier B.V. All rights reserved.

引用

页码：143 / 146

页数：4

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