Investigations into a low band gap, semiconducting polymer

被引:13
作者
Mills, CA [1 ]
Taylor, DM [1 ]
Murphy, PJ [1 ]
Dalton, C [1 ]
Jones, GW [1 ]
Hall, LM [1 ]
Hughes, AV [1 ]
机构
[1] Univ Coll N Wales, Inst Mol & Biomol Elect, Bangor LL57 1UT, Gwynedd, Wales
基金
英国工程与自然科学研究理事会;
关键词
electrochemical polymerisation; semiconducting films; low-bandgap conjugated polymers;
D O I
10.1016/S0379-6779(98)01170-9
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
A low bandgap polymer based on a carbon-bridged dithienyl monomer has been prepared by potentiostatic electrodeposition. Microscopic analysis of the polymer revealed a generally smooth morphology with scattered features protruding from the surface. Raman mapping shows the presence of a thickness dependent fluorescence in the film. Al/polymer/ITO Schottky diodes based on this new polymer show a small degree of rectification.
引用
收藏
页码:1000 / 1001
页数:2
相关论文
共 3 条
[1]   NARROW BANDGAP POLYMERS - POLY-4-DICYANOMETHYLENE-4H-CYCLOPENTA[2,1-B-3,4-B']DITHIOPHENE (PCDM) [J].
FERRARIS, JP ;
LAMBERT, TL .
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1991, (18) :1268-1270
[2]   SYNTHESIS OF CYCLOPENTADITHIOPHENONES [J].
JORDENS, P ;
RAWSON, G ;
WYNBERG, H .
JOURNAL OF THE CHEMICAL SOCIETY C-ORGANIC, 1970, (02) :273-&
[3]  
Skotheim T.A., 1986, HDB CONDUCTING POLYM