Surface pre-coating of talc particles by carboxyl methyl cellulose adsorption: Study of adsorption and consequences on surface properties and settling rate

被引:42
作者
Bacchin, P [1 ]
Bonino, JP
Martin, F
Combacau, M
Barthes, P
Petit, S
Ferret, J
机构
[1] Univ Toulouse 3, Lab Genie Chim, CNRS, UMR 5503, F-31062 Toulouse 9, France
[2] Univ Toulouse 3, CIRIMAT, CNRS, UMR 5085, F-31062 Toulouse 9, France
[3] CNRS, UMR 5563, Lab Mecanisme Transfert Geol, F-31062 Toulouse, France
[4] Univ Limoges, CNRS, UMR 6532, F-87060 Limoges, France
[5] Univ Poitiers, CNRS, UMR 6532, F-86022 Poitiers, France
[6] Talc Luzenac Europe SA, F-31036 Toulouse, France
关键词
talc; dispersion; coating; carboxyl methyl cellulose; adsorption; settling; hydrophobic; contact angle; wettability; zeta potential; aggregation;
D O I
10.1016/j.colsurfa.2005.07.026
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
This paper investigates the adsorption of different sized carboxyl methyl cellulose (CMC) onto talc particles (adsorption isotherm, adsorption reversibility), its consequences on the particles properties (electrophoretic mobility and surface wetting) and its effect on their dispersion (settling coefficient). Throughout the paper, the properties of talc particles dispersed in CMC solution are compared to CMC pre-coated talc particles: talc particles dried in a solution of CMC before their redispersion. The adsorption of CMC onto talc was quantified at around 0.4 mg of CMC per m(2) of talc and was seen to be irreversible on washing the talc particles with distilled water. When characterising talc surface properties, it was found that CMC adsorption leads to an increase of the negative surface charge and to an increase of the wettability. The settling velocity of CMC pre-coated talc particles in water can be around 50% lower than that of the initial talc particles. The pre-coating of talc particles by CMC is then assumed to increase their stabilization: particle aggregation is hindered by adsorbed CMC layer inducing electrosteric repulsion between the talc particles. The technique of talc pre-coating with CMC makes the talc dispersion easier and could open interesting perspectives in engineering processes using talc dispersions. (c) 2005 Elsevier B.V. All rights reserved.
引用
收藏
页码:211 / 219
页数:9
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