Fabrication of arrays of silver nanoparticle aggregates by microcontact printing and block copolymer nanoreactors

被引:14
作者
Cong, Y [1 ]
Fu, J [1 ]
Zhang, ZX [1 ]
Cheng, ZY [1 ]
Xing, RB [1 ]
Li, J [1 ]
Han, YC [1 ]
机构
[1] Chinese Acad Sci, Changchun Inst Appl Chem, Grad Sch, State Key Lab Polymer Phys & Chem, Changchun 130022, Peoples R China
关键词
block copolymers; micelles; nanoparticles;
D O I
10.1002/app.23063
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
A combination of microcontact printing and block copolymer nanoreactors succeeded in fabricating arrays of silver nanoparticle aggregates. A complex solution of polystyrene-block-poly(4-vinylpyridine) micelles and silver salt was used as an ink to form thin films or droplets on polydimethylsiloxane stamp protrusions. After these complex aggregates were printed onto silicon substrates under controlled conditions, highly ordered arrays of disklike, dishlike, and dotlike complex aggregates were obtained. A Subsequent oxygen reactive ion etching treatment yielded arrays of silver nanoparticle aggregates. (c) 2006 Wiley Periodicals, Inc.
引用
收藏
页码:2737 / 2743
页数:7
相关论文
共 51 条
[1]   DETERMINATION OF THE MICELLE ARCHITECTURE OF POLYSTYRENE POLY(4-VINYLPYRIDINE) BLOCK-COPOLYMERS IN DILUTE-SOLUTION [J].
ANTONIETTI, M ;
HEINZ, S ;
SCHMIDT, M ;
ROSENAUER, C .
MACROMOLECULES, 1994, 27 (12) :3276-3281
[2]  
Bernard A, 2000, ADV MATER, V12, P1067, DOI 10.1002/1521-4095(200007)12:14<1067::AID-ADMA1067>3.0.CO
[3]  
2-M
[4]   Characterization of polystyrene-block-poly(4-vinyl-pyridine) block copolymer micelles in toluene solution [J].
Calderara, F ;
Riess, G .
MACROMOLECULAR CHEMISTRY AND PHYSICS, 1996, 197 (07) :2115-2132
[5]  
Chen CC, 2001, ADV MATER, V13, P136, DOI 10.1002/1521-4095(200101)13:2<136::AID-ADMA136>3.3.CO
[6]  
2-P
[7]  
Choi YK, 2003, J PHYS CHEM B, V107, P3340, DOI [10.1021/jp0222649, 10.1021/JP0222649]
[8]   Brief review of metal nanoclusters in block copolymer films [J].
Ciebien, JF ;
Clay, RT ;
Sohn, BH ;
Cohen, RE .
NEW JOURNAL OF CHEMISTRY, 1998, 22 (07) :685-691
[9]   Metal film over nanosphere (MFON) electrodes for surface-enhanced Raman spectroscopy (SERS): Improvements in surface nanostructure stability and suppression of irreversible loss [J].
Dick, LA ;
McFarland, AD ;
Haynes, CL ;
Van Duyne, RP .
JOURNAL OF PHYSICAL CHEMISTRY B, 2002, 106 (04) :853-860
[10]  
Feldheim DL, 1998, CHEM SOC REV, V27, P1