Methine (CH) transfer via a chlorine atom abstraction/benzene-elimination strategy: Molybdenum methylidyne synthesis and elaboration to a phosphaisocyanide complex

被引：63

作者：

Agapie, T ^{[1
]}

Diaconescu, PL ^{[1
]}

Cummins, CC ^{[1
]}

机构：

[1] MIT, Dept Chem, Cambridge, MA 02139 USA

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2002年 / 124卷 / 11期

关键词：

D O I：

10.1021/ja017278r

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Methine (CH) transfer to an open coordination site was achieved in one pot by titanium(III) abstraction of Cl from 7-chloronorbornadiene, radical capture by Mo, and benzene extrusion. This efficient Mo methylidyne synthesis permitted elaboration to an anionic phosphaisocyanide derivative upon deprotonation, functionalization with dichlorophenylphosphine, and ultimate reduction. Copyright © 2002 American Chemical Society.

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页码：2412 / 2413

页数：2

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