Manganese(II) and palladium(II) complexes containing a new macrocyclic Schiff base ligand: antibacterial properties

被引：46

作者：

Anacona, JR

Bastardo, E

Camus, J

机构：

[1] Univ Oriente, Dept Quim, Cumana, Venezuela

[2] Univ Playa Ancha, Fac Ciencias, Valparaiso, Chile

来源：

TRANSITION METAL CHEMISTRY | 1999年 / 24卷 / 04期

关键词：

Physical Chemistry; Manganese; Inorganic Chemistry; Catalysis; Penicillin;

D O I：

10.1023/A:1006997706762

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Complexes of tetradentate macrocyclic Schiff base ligand, L, with Mn-II and Pd-II ions have been synthesized by the template condensation of 1,10-phenanthroline-2, 9-dicarboxaldehyde, 2,3-diamino-1,4-naphthoquinone and 1,2-dibromoethane in EtOH. The complexes were characterized by physicochemical and spectroscopic methods and an octahedral geometry is suggested for their structure. They have been screened for antibacterial activity against several bacteria, and the results are compared with the activity of penicillin.

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页码：478 / 480

页数：3

相关论文

共 15 条

[1]

ANACONA JR, 1995, TRANSIT METAL CHEM, V20, P239

[2]

BISHOP M, 1978, THESIS U CAMBRIDGE

[3] SYNTHESIS OF SOME 2,9-DISUBSTITUTED-1,10-PHENANTHROLINES [J].

CHANDLER, CJ ;

DEADY, LW ;

REISS, JA .

JOURNAL OF HETEROCYCLIC CHEMISTRY, 1981, 18 (03) :599-601

[4]

CHUNG LY, 1982, J CHEM SOC DA, P2127

[5] PREPARATION OF SOME IMIDAZOLE DERIVATIVES OF 1,4-NAPHTHOQUINONE [J].

HOOVER, JRE ;

DAY, AR .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1954, 76 (16) :4148-4152

[6] CHEMISTRY OF POLYDENTATE LIGANDS .5. COMPLEXES OF 2,9-DIHYDRAZINO-DERIVATIVES OF 1,10-PHENANTHROLINE - DEPENDENCE OF COORDINATION-NUMBER OF A LIGAND ON THE ANION PRESENT [J].

LEWIS, J ;

ODONOGHUE, TD .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1980, (05) :736-742

[7] CHEMISTRY OF POLYDENTATE LIGANDS .6. SYNTHESIS, CHARACTERIZATION, AND PROPERTIES OF GROUP 2B CATION COMPLEXES WITH NOVEL QUINQUEDENTATE MACROCYCLIC LIGANDS [J].

LEWIS, J ;

ODONOGHUE, TD .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1980, (05) :743-749

[8] CHEMISTRY OF POLYDENTATE LIGANDS .3. RING CLOSURES EFFECTED BY REACTION OF BETA-DIKETONES WITH 6,6'-DIHYDRAZINO-2,2-'-BIPYRIDYLNICKEL(11) AND 6,6'-DI(N-METHYLHYDRAZINO)-2,2'-BIPYRIDYLNICKEL(II) DIPERCHLORATE [J].

LEWIS, J ;

WAINWRIGHT, KP .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1978, (05) :440-446

[9] CHEMISTRY OF POLYDENTATE LIGANDS .2. MODE OF COORDINATION OF 6,6'-DIHYDRAZINO-2,2'-BIPYRIDYL LIGANDS WITH NICKEL(II) AND ZINC(II) IN OCTAHEDRAL COMPLEXES [J].

LEWIS, J ;

WAINWRIGHT, KP .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1977, (08) :739-744

[10] CHEMISTRY OF POLYDENTATE LIGANDS .1. CONDENSATION-REACTIONS OF ALDEHYDES AND KETONES WITH 6,6'-DIHYDRAZINO-2,2'-BIPYRIDYLNICKEL(II) PERCHLORATE [J].

LEWIS, J ;

WAINWRIGHT, KP .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1977, (08) :734-739