Reversible 3-Li storage reactions of amorphous phosphorus as high capacity and cycling-stable anodes for Li-ion batteries

被引：208

作者：

Qian, Jiangfeng ^{[2
]}

Qiao, Dan ^{[2
]}

Ai, Xinping ^{[1
]}

Cao, Yuliang ^{[1
]}

Yang, Hanxi ^{[2
]}

机构：

[1] Wuhan Univ, Hubei Key Lab Electrochem Power Sources, Wuhan 430072, Peoples R China

[2] Wuhan Univ, Coll Chem & Mol Sci, Wuhan 430072, Peoples R China

来源：

CHEMICAL COMMUNICATIONS | 2012年 / 48卷 / 71期

关键词：

BLACK PHOSPHORUS; PERFORMANCE;

D O I：

10.1039/c2cc34388f

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

An amorphous phosphorus/carbon nanocomposite demonstrates a reversible 3-Li storage capacity of 2355 mAh g(-1) with an excellent capacity retention of 90% over 100 cycles and a superior power capability with 62% of its capacity realizable at a very high rate of 8000 mA g(-1), possibly serving as a high capacity and high rate alternative anode for next-generation Li-ion batteries.

引用

页码：8931 / 8933

页数：3

共 24 条

[1] REFINEMENT OF CRYSTAL STRUCTURE OF BLACK PHOSPHOROUS [J].

BROWN, A ;

RUNDQVIST, S .

ACTA CRYSTALLOGRAPHICA, 1965, 19 :684-+

[2] Ternary and higher pnictides; prospects for new materials and applications [J].

Cameron, Jamie M. ;

Hughes, Robert W. ;

Zhao, Yimin ;

Gregory, Duncan H. .

CHEMICAL SOCIETY REVIEWS, 2011, 40 (07) :4099-4118

[3] High-performance lithium battery anodes using silicon nanowires [J].

Chan, Candace K. ;

Peng, Hailin ;

Liu, Gao ;

McIlwrath, Kevin ;

Zhang, Xiao Feng ;

Huggins, Robert A. ;

Cui, Yi .

NATURE NANOTECHNOLOGY, 2008, 3 (01) :31-35

[4] Facile synthesis and stable lithium storage performances of Sn- sandwiched nanoparticles as a high capacity anode material for rechargeable Li batteries [J].

Chen, Zhongxue ;

Cao, Yuliang ;

Qian, Jiangfeng ;

Ai, Xinping ;

Yang, Hanxi .

JOURNAL OF MATERIALS CHEMISTRY, 2010, 20 (34) :7266-7271

[5] Electrical Energy Storage for the Grid: A Battery of Choices [J].

Dunn, Bruce ;

Kamath, Haresh ;

Tarascon, Jean-Marie .

SCIENCE, 2011, 334 (6058) :928-935

[6] Characterization of amorphous and crystalline tin-cobalt anodes [J].

Fan, Quan ;

Chupas, Peter J. ;

Whittingham, M. Stanley .

ELECTROCHEMICAL AND SOLID STATE LETTERS, 2007, 10 (12) :A274-A278

[7] Multi-electron reaction materials for high energy density batteries [J].

Gao, Xue-Ping ;

Yang, Han-Xi .

ENERGY & ENVIRONMENTAL SCIENCE, 2010, 3 (02) :174-189

[8] Study of the electrochemical performance of sputtered Si1-xSnx films [J].

Hatchard, TD ;

Dahn, JR .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2004, 151 (10) :A1628-A1635

[9] Tin-based amorphous oxide: A high-capacity lithium-ion-storage material [J].

Idota, Y ;

Kubota, T ;

Matsufuji, A ;

Maekawa, Y ;

Miyasaka, T .

SCIENCE, 1997, 276 (5317) :1395-1397

[10] CRYSTAL STRUCTURES ADOPTED BY BLACK PHOSPHORUS AT HIGH PRESSURES [J].

JAMIESON, JC .

SCIENCE, 1963, 139 (356) :1291-&

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